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Nitrosyl-Centered Redox and Acid–Base Interconversions in ...

Jan 07, 2014 · This work reports the preparation of a new 6-coordinated nitrosyl compound and its use as a model to explore the redox and acid–base properties of the three redox states of bound nitrosyl (formally NO+, NO•, NO–/HNO) in {RuNO}6,7,8 species. We prepared the octahedral {RuNO}6 complex [Ru(Me3[9]aneN3)(bpy)(NO)]3+ (Me3[9]aneN3: 1,4,7-trimethyl-1,4,7-triazacyclononane; bpy = 2,2 ...

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Remarkable Changes of the Acidity of Bound Nitroxyl (HNO ...

This work demonstrates that the acidity of nitroxyl (HNO) coordinated to a metal core is significantly influenced by its coordination environment. The possibility that NO– complexes may be the predominant species in physiological environments has implications in bioinorganic chemistry and biochemistry. This (apparently simple) result pushed us to delve into the basic aspects of HNO ...

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Remarkable Changes of the Acidity of Bound Nitroxyl (HNO ...

This work demonstrates that the acidity of nitroxyl (HNO) coordinated to a metal core is significantly influenced by its coordination environment. The possibility that NO– complexes may be the predominant species in physiological environments has implications in bioinorganic chemistry and biochemistry. This (apparently simple) result pushed us to delve into the basic aspects of HNO ...

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STAR WARS: The Old Republic - Heroic +2

May 24, 2012 · Heroic +2. Given the issues finding more than a handful of people on the midrange planets, I think Heroic+2 missions beyond the origin planet should be doable with a companion. Some are almost doable with good tactics, and it wouldn't take much to nudge the difficulty down a tad for 1 player and a companion. I think this would help round out XP ...

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Maidla | Mass Effect Wiki | Fandom

Location: Milky Way /Hades Gamma /Plutus System / Second planet Maidla is a terrestrial planet with a light atmosphere of carbon dioxide and hydrogen sulfide. The surface is hot, and mainly composed of magnesia with deposits of sulfur. Over a dozen volcanoes are erupting across the surface.

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Xathorron | Mass Effect Wiki | Fandom

Location: Milky Way /Attican Beta /Hercules System / First planet Xathorron is a small rock planet, with a thin atmosphere of carbon dioxide and hydrogen sulfide. The surface is scorching hot, and mainly composed of sulfur with deposits of boron. The planet's moons are an uncommon source of rhodamine. The dye can be found in mineral deposits.

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